First enantioselective synthesis of methyl (+)-7-methoxyanodendroate, an antitubercular dihydrobenzofuran.

Abstract

An enantioselective synthesis of Me (+)-7-methoxyanodendroate was achieved utilizing a Claisen rearrangement, a Grubbs cross-metathesis, and a Shi epoxidn.-cyclization sequence, confirming the abs. configuration assigned to the natural product.

Publication
Tetrahedron Letters
Date